Heterogeneous modeling for fixed-bed Fischer-Tropsch synthesis: Reactor model and its applications

A comprehensive one-dimensional heterogeneous reactor model is developed to simulate the performance of fixed-bed Fischer-Tropsch reactors for hydrocarbon production. The detailed mechanistic kinetics is combined into the reactor model along with considering the fact that the catalyst pores are filled with liquid wax under realistic conditions. The equilibrium between the gases in the bulk and the wax in the catalyst pores is correlated by using a modified SRK equation of state (MSRK EOS). The model is solved by using Gear method to integrate the reactor model with the embedded pellet model discretized by orthogonal collocation on finite elements. The validity of the reactor model is tested against the measured data from different-scale demonstration processes. Satisfactory agreements between model predictions and experiment results are obtained. Detailed numerical simulations are performed to investigate the effect of major process parameters on the reaction behavior of fixed-bed FTS systems with recycle operation. (C) 2003 Elsevier Science Ltd. All rights reserved.