Journal
TETRAHEDRON LETTERS
Volume 44, Issue 6, Pages 1179-1182Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)02830-7
Keywords
selenium and compounds; Diels-Alder reactions; dienoates; seleniranes
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Selenoaldehydes, regenerated by thermal retro Diels-Alder reaction of anthracene cycloadducts under neutral conditions, reacted with 2-methoxyfuran to give methyl penta-2,4-dienoates along with the deposition of elemental selenium. In a similar reaction with 2-methoxyfuran using thioaldehyde, thiirane compound was isolated. This suggests the formation of selenirane intermediates in the above reaction. (C) 2003 Published by Elsevier Science Ltd.
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