Journal
ORGANIC LETTERS
Volume 5, Issue 3, Pages 349-352Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol027382t
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A copper-free palladium-mediated cleavage of O/N-propargyl bonds in aqueous media has been investigated, affording a mild and convenient method for the deprotection of phenols and anilines. The methodology could be utilized for the selective removal of propargyl groups from aryl ethers and amines without affecting a variety of unprotected functional groups present in the substrates. The mechanism and scope of the reaction is discussed.
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