Journal
ORGANIC LETTERS
Volume 5, Issue 3, Pages 235-237Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol026947i
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[GRAPHICS] Catalytic Sc(OTf)(3) greatly increases the efficiency of hydrogen peroxide mediated monooxidation of alkyl-aryl sulfides and methyl cysteine containing peptides. The method is high yielding, compatible with many widely used protecting groups, suitable for solid-phase applications and proceeds with minimum over-oxidation.
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