4.7 Article

A new metal-organic open framework consisting of threefold parallel interwoven (6,3) nets

Journal

INORGANIC CHEMISTRY
Volume 42, Issue 3, Pages 676-678

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic025983a

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Threefold parallel interwoven (6,3) nets were assembled from Ni(II) cyclam complex and 1, 3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]benzene. The network generates triangular voids of effective size ca. 18.4 x 14.7 x 9.5 Angstrom. It contains 35% free volume of the crystal volume and is stable up to 300 degreesC.

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