Journal
CARBOHYDRATE POLYMERS
Volume 51, Issue 3, Pages 255-264Publisher
ELSEVIER SCI LTD
DOI: 10.1016/S0144-8617(02)00160-1
Keywords
spruce; birch; alkaline degradation; cellulose; hemicelluloses; molar mass distribution; size exclusion chromatography; kraft pulp; fibre strength
Categories
Ask authors/readers for more resources
The alkaline degradation of birch and Norway spruce during kraft pulping was studied on a laboratory scale by two degradation strategies, by varying the pulping time using the same initial alkali level and by varying the initial alkali concentration using a constant time. The degradation at the molecular level was monitored by determining the carbohydrate composition, intrinsic viscosity and-molecular mass distribution (MMD). The influence of the degradation on fibre strength was studied as zero-span tensile index. The alkaline degradation was to a large extent homogeneous on a molecular level. However, some significant differences in degradation patterns were found. In the case of birch, the two different degradation strategies (increased alkali level and increased pulping time) caused differences in MMD and fibre strength (comparisons made at a given intrinsic viscosity or M-w). For spruce pulps, the decrease in fibre strength and the shift in MMD were the same in both series, regardless of degradation strategy. (C) 2003 Elsevier Science Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available