Journal
FLUID PHASE EQUILIBRIA
Volume 204, Issue 2, Pages 295-302Publisher
ELSEVIER
DOI: 10.1016/S0378-3812(02)00265-0
Keywords
room temperature ionic liquid; mixture; phase equilibria; DSC; Raman spectrum; ab initio calculation
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A new room temperature ionic liquid (RTIL) has been prepared by directly Mixing InCl3 and 1-ethyl-3-methylimidazolium chloride (EMIC) under dry nitrogen atmosphere. The phase diagram of the binary system InCl3-EMIC was determined by DSC. Both Raman scattering and ab inito calculations indicate that InCl4- is the predominant indium-containing species in the ionic liquid. And it was further confirmed by NMR experiments. (C) 2002 Elsevier Science B.V. All rights reserved.
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