Journal
ORGANIC LETTERS
Volume 5, Issue 4, Pages 587-590Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol027575g
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- NIGMS NIH HHS [GM-29028] Funding Source: Medline
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[GRAPHICS] The total synthesis of (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-5, a highly efficient union of the eastern and western fragments (-)-5 and 4, respectively, exploiting our 2-substituted indole synthesis, and a new protocol for the construction of ring C.
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