Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 4, Pages 1601-1602Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0262560
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The first Oppenauer oxidation of primary alcohols with acetone or 2-butanone by an amino alcohol-based Ir bifunctional catalyst was accomplished. The reaction proceeds with 1 mol % catalyst in acetone or 2-butanone at 30-80 degreesC to give the corresponding aldehydes in 33-96% yield.
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