Journal
PHYSICAL REVIEW B
Volume 67, Issue 10, Pages -Publisher
AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevB.67.104502
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We have performed a study of the Raman active modes of beta-HfNCl, beta-ZrNCl, and beta-ZrNBr and Na-doped beta-HfNCl in various scattering configurations. The experimental values are compared with a lattice dynamical calculation and assigned to definite atomic motions. The variation of the atomic force constants are analyzed as a function of the bond length, relating their relative strength with the atomic characteristics of the compound.
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