Journal
PHYTOCHEMISTRY
Volume 62, Issue 5, Pages 723-732Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0031-9422(02)00517-4
Keywords
Xanthomonas campestris pv. zinniae; bacterial detoxification; perylenequinone; phototoxin; xanosporolactone; xanosporic acid
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The red fungal perylenequinone phototoxin cercosporin is oxidized by Xanthomonas campestris pv zinniae to a non-toxic, unstable green metabolite xanosporic acid, identified via its lactone as 1,12-bis(2'R-hydroxypropyl)-4,9-dihydroxy-6,7-methylenedioxy-11-methoxy-3-oxaperylen-10H-10-one-2-carboxylic acid. Xanosporolactone was isolated in approximately 2:1 ratio of MY atropisomers. (C) 2003 Elsevier Science Ltd. All rights reserved.
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