Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 24, Issue 3, Pages 274-277Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200390041
Keywords
biomimetic synthesis; biomineralization; CaCO3; microencapsulation; polyelectrolyte capsule; urease
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A new biomimetic approach for performing CaCO3 synthesis exclusively inside micron-sized polyelectrolyte capsules, based on the fermentative formation of a precipitative agent (CO32- anion) by urease-catalyzed urea hydrolysis, was developed. Precipitated CaCO3 completely fills the interior capsule volume and has a metastable waterite phase.
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