4.3 Article

Sequential carbometalation/elimination reaction takes place between gallium enolate and chloroethyne

Journal

CHEMISTRY LETTERS
Volume 32, Issue 3, Pages 298-299

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.298

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In the presence of GaCl3, silyl enol ethers are sequentially ethynylated at the a-carbon atom with chlorotrimethylsilyl-ethyne giving (alpha-enynylated, (alpha-endiynylated and alpha-entriynylated ketones.

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