4.8 Article

First synthesis of perfluorinated corrole and its Mn=O complex

Journal

ORGANIC LETTERS
Volume 5, Issue 5, Pages 617-620

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol027111i

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[GRAPHICS] A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(Ill) and oxomanganese(V) derivatives have been synthesized. The perfluorinated manganese corrolate exhibited excellent reactivity and stability in the catalytic oxidation of alkenes with iodosylbenzene.

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