Journal
ORGANIC LETTERS
Volume 5, Issue 5, Pages 669-672Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol027406w
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[GRAPHICS] A heteroatom-tethered regloselective ring-closing metathesis reaction was used for the C-19 functionalization of 1alpha-hydroxy-5,6-trans-vitamin D-2 analogues. Applications of the reaction to form a range of analogues by manipulation of the tether using both organolithium reagents and Diels-Alder cycloadditions are described.
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