Improvements in thermospray flame furnace atomic absorption spectrometry

In thermospray flame furnace atomic absorption spectrometry (TS-FF-AAS) a nickel atomization tube is placed in the acetylene/air flame on a holder built onto a standard AAS burner head. The liquid to be analyzed is transported by a low or high-pressure pump through a very hot, simple, inexpensive ceramic capillary tip acting as a flame-heated thermospray into the flame furnace. This results in complete sample introduction and increases the residence time of the sample in the absorption volume. This leads for 17 elements to a 3-110-fold improvement in the power of detection compared to conventional flame AAS. The absolute detection limits (3s values, N = 25) lie between 0.2 mug 1(-1) (Zn) and 310 mug 1(-1) (Se) according to the element. The R.S.D. (N = 15) is 1.4-5.5% according to the element and applied concentration. TS-FF-AAS can easily be incorporated on any standard flame AAS instrument and can be automated with a standard autosampler. (C) 2002 Elsevier Science B.V. All rights reserved.