Journal
TETRAHEDRON
Volume 59, Issue 12, Pages 2185-2189Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00151-0
Keywords
ester aminolysis; microwave irradiation; solvent-free reactions; dielectric characteristics; phase transfer catalysis
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Solvent-free ester aminolysis was studied under microwave or conventional heating either in the absence of base or induced by KOtBu with or without a phase transfer agent. The specific microwave effects were shown to be dependent on the conditions and discussed in terms of relative polarities of ground and transition states. (C) 2003 Elsevier Science Ltd. All rights reserved.
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