Journal
CHEMICAL PHYSICS LETTERS
Volume 371, Issue 1-2, Pages 29-34Publisher
ELSEVIER
DOI: 10.1016/S0009-2614(03)00226-4
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The elementary reaction of formaldehyde (H2CO) with chlorine atom has been experimentally investigated by the time-resolved infrared emission spectroscopy. The nascent products HCO and HCl (v less than or equal to 3) are observed. The major product channel has been identified as Cl + H2CO --> HCl + HCO. Theoretical calculations have revealed that the mechanism is a nearly barrierless peripheral hydrogen abstraction reaction. (C) 2003 Elsevier Science B.V. All rights reserved.
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