Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 6, Issue 4, Pages 398-401Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(02)00797-9
Keywords
N-confused porphyrin; isoporphyrin; zinc complex; organometallics; side-on eta(1)-coordination
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A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by H-1 NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Angstrom longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on eta(1)-coordination with the inner-core-carbon in 2-Zn. (C) 2002 Elsevier Science B.V. All rights reserved.
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