Journal
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Volume 33, Issue 4, Pages 683-698Publisher
MARCEL DEKKER INC
DOI: 10.1081/SIM-120020332
Keywords
mixed-ligand; Ni(II) picrate complexes; spin free octahedral; medicine in homeopathy
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The present communication describes the synthesis of some mixed-ligand hexacoordinated picrato complexes of nickel(II) of the composition [Ni(PA)(2)(L-L)(2)], where PAH=picric acid and L-L=2-aminobenzothiazole (ABZT), 2-(2'-aminophenyl)benzothiazole (2'-AMPHBZT), 2-(3'-aminophenyl)benzothiazole (3'-AMPHBZT), bipyridine (bpy), o-phenanthroline (phen) or 2,6-bis(benzimidazyl)pyridine (BBZLPY). These complexes were obtained by the interaction of nickel(II) picrate with the corresponding ligands L-L in methanol. The resulting compounds have been characterized by elemental analyses, magnetic, molar conductance and decomposition temperature measurements, electron spin resonance, infrared and electronic spectral studies. All the complexes are thermally stable and behave as non-electrolytes. An octahedral structure has been tentatively proposed for these complexes.
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