Journal
GEOCHIMICA ET COSMOCHIMICA ACTA
Volume 67, Issue 8, Pages 1589-1595Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0016-7037(02)01283-8
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The enantiomeric and carbon-isotopic composition of the amino acid isovaline have been analyzed in several samples of the Murchison meteorite and one sample of the Murray meteorite. L-Enantiomeric excesses of the amino acid were found to range from 0 to 15.2%, varying significantly both between meteorite stones and at short distances within a single stone. The upper limit of this range is the largest enantionteric excess measured to date for a biologically rare meteoritic amino acid and raises doubts that circularly polarized light irradiation could have been the sole cause of amino acids chiral asymmetry in meteorites. Individual D-and L-isovaline delta(13)C values ware found to be about + 18parts per thousand, with no significant differences between the two enantiomers to suggest terrestrial contamination. The amino acid relative abundance also varied between samples, with isovaline/alanine ratios of 0.5 to 6.5. X-ray diffraction analyses of contiguous meteorite fragments suggest a possible correlation between isovaline and hydrous silicates abundances. Copyright (C) 2003 Elsevier Science Ltd.
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