Spin structure of the nucleon at low energies

The spin structure of the nucleon is analyzed in the framework of a Lorentz-invariant formulation of baryon chiral perturbation theory. The structure functions of doubly virtual Compton scattering are calculated to one-loop accuracy (fourth order in the chiral expansion). We discuss the generalization of the Gerasimov-Drell-Hearn sum rule, the Burkhardt-Cottingham sum rule and other moments of the nucleon spin structure functions. We give predictions for the forward and the longitudinal-transverse spin polarizabilities of the proton and the neutron at zero and finite photon virtuality. A detailed comparison to results obtained in heavy baryon chiral perturbation theory is also given.