Journal
CATALYSIS SURVEYS FROM ASIA
Volume 7, Issue 1, Pages 21-29Publisher
KLUWER ACADEMIC/PLENUM PUBL
DOI: 10.1023/A:1023428523640
Keywords
electrocatalyst; platinum; ruthenium; PtRu; platinum complex; ruthenium complex; methanol; oxidation; carbon monoxide; fuel cell; DMFC
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Well-homogenized PtRu/C electrocatalysts possessing high specific activity for methanol electro-oxidation were prepared by a co-impregnation method from carbon black and ethanolic solutions of Pt(NH3)(2)(NO2)(2) and RuNO(NO3)(x). The specific activity for methanol electro-oxidation increased with an increase in the PtRu particle size. A similar size effect was observed for Pt/C electrocatalysts. The size effect was discussed by considering a model catalyst method.
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