Journal
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
Volume 30, Issue 7, Pages 1511-1517Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ja00068h
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Funding
- U.S. Department of Energy through the LANL/LDRD Program under Seaborg Institute Postdoctoral Fellowship program
- Next Generation Safeguards Initiative (NGSI), Office of Nonproliferation and International Security (NIS), National Nuclear Security Administration (NNSA)
- National Nuclear Security Administration [DE-AC52-06NA25396. LA-UR-15-20897]
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The measurement of plutonium (Pu) in a soil matrix is of interest in safeguards, nuclear forensics, and environmental remediation activities. The elemental composition of two Pu contaminated soil particles was characterized nondestructively using micro X-ray fluorescence spectrometry (micro-XRF) techniques including high resolution X-ray (hiRX) and 3D confocal XRF. The three dimensional elemental imaging capability of confocal XRF permitted the identification two distinct Pu particles within the samples: one external to the Fe-rich soil matrix and another co-located with Cu within the soil matrix. The size and morphology of the particles was assessed with X-ray transmission microscopy (XTM) and micro X-ray computed tomography (micro-CT) providing complementary information. Limits of detection for a 30 mu m Pu particle are <15 ng for each of the XRF techniques. This study highlights the capability for lab-based, nondestructive, spatially resolved characterization of heterogeneous matrices on the micrometer scale with nanogram sensitivity.
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