Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 107, Issue 13, Pages 2887-2891Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp026484y
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Changes in the electronic structure of Li1-xNi0.8Co0.2O2 during delithiation (charge) are elucidated by changes in the 0 K-edge and transition-metal (TM) L-2,L-3-edge. Electron energy-loss spectrometry was used to investigate the 0 2p and TM 3d occupancy over a wide range of lithium concentrations. Quantitative analysis of the TM L-2,L-3 white lines indicates that the Ni ion accommodates no more than one-half of an electron, whereas the net Co valence is unaffected by delithiation. In contrast with the small changes observed in the TM L-2,L-3-edge, a large decrease in state occupancy is observed in the near-edge structure of the 0 K-edge, suggesting that much of the electron charge is accommodated by the anion.
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