Journal
ORGANIC LETTERS
Volume 5, Issue 7, Pages 1119-1122Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0342002
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- NIGMS NIH HHS [GM 63167] Funding Source: Medline
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[GRAPHIC] The geometrical isomers of 6-ethylidenedioxadisilacyclohexane were prepared by intramolecular hydrosilylation of an unsymmetrical disiloxane by the use of Pt (syn) and Ru (anti) catalysts. This new class organosilicon reagents underwent cross-coupling reactions with a range of aryl iodides to afford (E)- and (2)-trisubstituted allylic alcohols in a highly stereospecific fashion.
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