Journal
ORGANIC LETTERS
Volume 5, Issue 7, Pages 1071-1074Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol034093b
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[GRAPHIC] p-tert-Butylcalix[5]arenes in a fixed cone conformation, endowed with a urea functionality at the upper rim, behave as remarkably efficient abiotic receptors of omega-amino acids and biogenic amines, which are bound with one end of the chain within the pi-basic cavity (primary recognition site) and the other grasped by the secondary hydrogen bonding donor/acceptor binding site.
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