Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 7, Pages 2929-2933Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo026877t
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Reaction of the catalyst 1 or Pd(OAc)(2) with tetrabutylammonium acetate, dissolved in tetrabutylammonium bromide, leads to a fast formation of Pd nanoparticles which efficiently catalyze the stereospecific reaction of cinnamates with aryl halides to give beta-aryl-substituted cinnamic esters. The role of tetrabutylammonium. acetate is crucial in determining the formation of nanoparticles and stereospecificity of the C-C coupling process.
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