Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 7, Pages 2741-2747Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo026323q
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Four new tetradentate 2,6-disubstituted pyridine and tridentate 2-substituted pyridine ligands were synthesized. Two of these compounds possessed a metal ion binding subunit in the form of a 2,6-disubstituted-4-N,N'-dimethylamine pyridine moiety. Cu2+-complexes of these ligands incorporated in cetyltrimethylammonium bromide (CTABr) micelles speeded the cleavage of p-nitrophenyldiphenyl phosphate and p-nitrophenyl hexanoate at pH 7.6. On the basis of a kinetic version of Job plot analysis, a 1:1 ligand/Cu2+ stoichiometry was found to be the most active species. In CTABr micelles, the pK(a) values for the Cu2+-coordinated hydroxyl or pendant -CH2OH in these ligands were between 7.8 and 7.9. The metallomicellar systems displayed catalytic (turnover) behavior in the presence of excess substrates.
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