Journal
SYNTHETIC METALS
Volume 137, Issue 1-3, Pages 1201-1202Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0379-6779(02)00988-8
Keywords
electrocrystallization; BEDT-TTF; self-assembly using surface chemistry; polycrystalline thin films; Raman spectroscopy
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Densely covered (ET)X, thin films can be selectively electrodeposited on gold electrodes. The insulating (ET)X, films are converted to (ET)(2)X conductive films through a novel conproportionation reaction. Both ET and ET salt patterns can be prepared with the PDMS stamping technique with use of an ET derivative with a dodecanethiol chain for surface derivatization. These solution procedures open up the possibility to prepare conductive and superconductive charge-transfer salt thin films as well as patterns.
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