4.3 Article

Regulation of main-chain conformation of permethyldecasilane by complexation with γ-cyclodextrin

Journal

CHEMISTRY LETTERS
Volume 32, Issue 4, Pages 380-381

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.380

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An absorption and emission spectroscopic study of an inclusion complex of permethyldecasilane (1) with gamma-cyclodextrin in water has shown that the silicon main chain of 1 has an alltrans rod-like conformation in the hydrophobic cavities of gamma-cyclodextrin at room temperature.

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