Journal
CHEMISTRY LETTERS
Volume 32, Issue 4, Pages 360-361Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.360
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Several propargylhydrazines were prepared and then oxidized by manganese dioxide to generate short-lived 1,1-diazenes, which produced novel allenyl azo compounds (8) through [2,3] sigmatropic rearrangement. Isomerization of 8 or nucleophilic addition to the title compounds lead to hydrazones as well as pyrazole derivatives.
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