Journal
TETRAHEDRON
Volume 59, Issue 15, Pages 2657-2665Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00309-0
Keywords
FR901483; azaspiro compounds; oxazines; nitrogen heterocycles; cyclization
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Haloaminocyclization reactions of polysubstituted gamma-aminocyclohexenes give 3-amino-1-azaspiro[4.5]decan-8-one derivatives. The stereocontrol, chemoselectivity (N-attack vs O-attack), and influence of the halonium ion are discussed. (C) 2003 Elsevier Science Ltd. All rights reserved.
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