☆ 4.4 Article

A convenient synthesis of tetrazole, precursors of α-dialkylated α-amino acids, by reaction of trimethylsilyl azide with α-dialkylated β-ketoesters

TETRAHEDRON LETTERS (2003)

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Journal

TETRAHEDRON LETTERS
Volume 44, Issue 15, Pages 3179-3181

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)00444-1

Keywords

Schmidt rearrangement; beta-keto ester; trimethylsilyl azide; tetrazole; amino acids

Categories

Chemistry, Organic

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The Schmidt rearrangement using trimethylsilyl azide with various alpha-dialkylated beta-keto esters affords a convenient synthesis of tetrazole, precursors of a-dialkylated a-amino acids. (C) 2003 Elsevier Science Ltd. All rights reserved.

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