Journal
MACROMOLECULES
Volume 36, Issue 7, Pages 2198-2205Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma021608q
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Novel polystyrenes (PS) carrying thymine functional groups were synthesized by copolymerizing styrene (St) and 1-(vinylbenzyl)thymine (1-VBT) in the presence and absence of divinylbenzene (DVB) in batch free radical emulsion polymerization. Microsphere latexes were obtained with an average particle size of approximate to60 nm (3.0 and 5.0 wt % [VBT](0)) with approximate to80% conversion and approximate to38 nm (10 wt % [VBT](0)) with 91% conversion. The final copolymer latexes were freeze-dried to obtain particles in the size range of 32-544 mum. Copolymer compositions were determined by FTIR-DRIFT, H-1 NMR, and elemental analysis and were found to be close to the composition of the monomer charges. XPS analysis revealed that VBT concentration on the surface of the particles was much higher (17, 24, and 36 wt %) than in the bulk. Phenol was selected as a model compound to examine adsorption onto the thymine functional groups. Hydrogen bonding between the phenolic hydroxyl group and the thymine units of soluble polymers was evidenced by H-1 NMR and FTIR spectroscopy. Adsorption isotherms obtained with all samples showed a good fit with Langmuir's model, supporting evidence for a monolayer chemisorption model in the heterogeneous adsorbent-phenol/hexane system investigated. 89.4% of the phenol was desorbed by adding Borax buffer solution of pH greater than or equal to 10 to the adsorbent-phenol/hexane system. These novel copolymers have potential in biotechnology.
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