Journal
ORGANIC LETTERS
Volume 5, Issue 8, Pages 1213-1215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0340989
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- NIGMS NIH HHS [GM53818] Funding Source: Medline
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The incorporation of [N-15, O-18]-isobutylhydroxylamine into the antibiotic valanimycin by Streptomyces viridifaciens has been shown to proceed with loss of the O-18 label, thereby demonstrating that the azoxy oxygen atom of valanimycin is not derived from the oxygen atom of isobutylhydroxylamine.
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