4.8 Article

The first example of Nazarov reactions of vinyl cumulenyl ketones

Journal

ORGANIC LETTERS
Volume 5, Issue 8, Pages 1171-1174

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol034110x

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Funding

  1. NIGMS NIH HHS [GM57873] Funding Source: Medline

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alpha-Lithio cumulenyl ethers can be prepared in situ and converted to alpha-allenyl cyclopentenones. Isomerization of the product of one such reaction has led to a furanyl cyclopentenone, the core structure of nakadomarin A.

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