Journal
TETRAHEDRON LETTERS
Volume 44, Issue 17, Pages 3547-3549Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(03)00581-1
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A new chiral ligand was prepared in a convenient two-step procedure starting from an asymmetric diamination reaction. Subsequent treatment of the resulting osmaimidazolidine with a phenyl Grignard reagent and titanium tetra(iso-propoxide) furnished a complex that catalyses asymmetric dialkylzinc additions to aromatic aldehydes. (C) 2003 Elsevier Science Ltd. All rights reserved.
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