Laser induced morphology change of silver colloids: formation of nano-size wires

We have performed laser irradiation at 355 nm onto spherical silver colloids in pure water, which were prepared by laser ablation of silver plate in pure water. In addition to size-reduced particles due to fragmentation, we have found that nano-size wire structures were formed in solution for the first time. The width of the wires was in the 10-100 nm range, and the length of long wires was more than 1 mum. Electron diffraction patterns revealed that these wires were composed of pure silver. It was suggested that the wires were formed via fusion of particles photo-thermally melted by laser irradiation. (C) 2003 Elsevier Science B.V. All rights reserved.