4.8 Article

Dirhodium tetraprolinate-catalyzed asymmetric cycloproplanations with high turnover numbers

Journal

ORGANIC LETTERS
Volume 5, Issue 9, Pages 1403-1406

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol034002a

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graphic The bridged dirhodium tetraprolinate Rh-2(S-biTISP)(2) (2) catalyzes the asymmetric cyclopropanation reaction between methyl phenyldiazoacetate and styrene at room temperature with high turnover number (92 000) and turnover frequency (4000 per h).

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