Journal
ORGANIC LETTERS
Volume 5, Issue 9, Pages 1547-1550Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0300266
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A highly stereoselective preparation of novel chiral (E)-alpha-haloenamides under mild conditions utilizing magnesium halide salts is described. This unexpected mild and efficient hydrohalogenation reaction highlights another synthetic utility of ynamides.
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