Dispersion modelling of air pollution caused by road traffic using a Markov Chain-Monte Carlo model

Although the strict legislation regarding vehicle emissions in Europe (EURO 4, EURO 5) will lead to a remarkable reduction of emissions in the near future, traffic related air pollution still can be problematic due to a large increase of traffic in certain areas. Many dispersion models for line-sources have been developed to assess the impact of traffic on the air pollution levels near roads, which are in most cases based on the Gaussian equation. Previous studies gave evidence, that such kind of models tend to overestimate concentrations in low wind speed conditions or when the wind direction is almost parallel to the street orientation. This is of particular interest, since such conditions lead generally to the highest observed concentrations in the vicinity of streets. As many air quality directives impose limits on high percentiles of concentrations, it is important to have good estimates of these quantities in environmental assessment studies. The objective of this study is to evaluate a methodology for the computation of especially those high percentiles required by e.g. the EU daughter directive 99/30/EC (for instance the 99.8 percentile for NO2). The model used in this investigation is a Markov Chain - Monte Carlo model to predict pollutant concentrations, which performs well in low wind conditions as is shown here. While usual Lagrangian models use deterministic time steps for the calculation of the turbulent velocities, the model presented here, uses random time steps from a Monte Carlo simulation and a Markov Chain simulation for the sequence of the turbulent velocities. This results in a physically better approach when modelling the dispersion in low wind speed conditions. When Lagrangian dispersion models are used for regulatory purposes, a meteorological pre-processor is necessary to obtain required input quantities like Monin-Obukhov length and friction velocity from routinely observed data. The model and the meteorological pre-processor applied here, were tested against field data taken near a major motorway south of Vienna. The methodology used is based on input parameters, which are also available in usual environmental assessment studies. Results reveal that the approach examined is useful and leads to reasonable concentration levels near motorways compared to observations.