Journal
PHYSICAL REVIEW A
Volume 67, Issue 5, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevA.67.050501
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Analysis and assignment of spectra involving the lowest excited states of the heavier alkali-metal atom dimers are complicated by the strong spin-orbit coupling elements. Here we report an analysis of the Fourier-transform spectroscopy data from laser-induced fluorescence of the coupled A (1)Sigma(+) and b (3)Pi states of RbCs, using the discrete variable representation. Fitted parameters are given and special effects due to strong coupling are discussed.
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