A light-emitting diode fabricated from horse-heart cytochrome c

We have fabricated a light-emitting diode from horse-heart cytochrome c and measured the electro-luminescence (EL) spectra. The spectra exhibit broad peaks around 530 and 690 nm, and a weak shoulder around 410 nm. The EL spectra are completely different from the photo-luminescence spectra previously reported. The appearance of the 690 nm emission band suggests the charge-transfer between the iron and the axial methionine ligand plays a crucial role in the electrical conduction in the cytochrome c film. (C) 2003 Elsevier Science Ltd. All rights reserved.