Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 9, Pages 3599-3602Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo026894i
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A new synthetic method of organoselenium compounds has been developed. When phenyl tributylstannyl selenide (PhSeSnBu3) was allowed to react with acyl or aroyl chlorides in the presence of a catalytic amount of a palladium complex such as Pd(PPh3)(4), Se-phenyl selenol esters were obtained in moderate to good yields. Similarly, the palladium complex catalyzed the reaction of PhSeSnBu3 with alpha-halo carbonyl compounds to afford the corresponding alpha-phenyseleno carbonyl compounds in moderate yields.
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