Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 68, Issue 9, Pages 3658-3662Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo020683w
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Methyl protodioscin (1), otherwise known as 3-O-[alpha-L-rhamnopyranosyl-(1-->2)-{alpha-L-rhamnopyranosyl-(1-->4) }-beta-D-glucopyranosyl]-26-O-[beta-D-glucopyranosyl]-22-methoxy-25(R)-furost-5-ene-3beta,26-diol, has been synthesized for the first time from diosgenin through nine steps in an overall yield of 7.8%.
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