4.4 Article

Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C60-porphyrin light-to-photocurrent conversion system

Journal

TETRAHEDRON
Volume 59, Issue 19, Pages 3537-3540

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00417-4

Keywords

fullerenes; calixarenes; porphyrins; cyclodextrins; photocurrent

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In a light-to-photocurrent conversion system based on a C-60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units. (C) 2003 Elsevier Science Ltd. All rights reserved.

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