4.3 Article

Catalytic and β-stereoselective mannosylation of several glycosyl acceptors with mannosyl 6-nitro-2-benzothiazoate

Journal

CHEMISTRY LETTERS
Volume 32, Issue 5, Pages 442-443

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2003.442

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Mannosylation of several glycosyl acceptors with a novel mannosyl donor having the 6-nitro-2-benzothiazoate function at an anomeric position proceeded smoothly in the presence of a catalytic amount of tetrakis(pentafluorophenyl)boric acid [HB(C6F5)(4)] to afford the corresponding disaccharides in high yields with good to high beta-stereoselectivities.

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