Journal
TETRAHEDRON
Volume 59, Issue 19, Pages 3493-3498Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00471-X
Keywords
oxidation; supported reagents; solid-phase synthesis
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Pyridinium chlorochromate adsorbed on neutral alumina (PCC-Al2O3) under solvent-free conditions has been found to oxidize primary aliphatic alcohols to alkyl alkanoates whereas primary benzylic and primary allylic alcohols produce the corresponding aldehydes. Secondary aliphatic and aromatic alcohols produce ketones without isomerization and polymerization of double bonds, overoxidation and other side-reactions. (C) 2003 Elsevier Science Ltd. All rights reserved.
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