4.4 Article

Al2O3/MeSO3H (AMA) as a new reagent with high selective ability for monoesterification of diols

Journal

TETRAHEDRON
Volume 59, Issue 20, Pages 3627-3633

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(03)00518-0

Keywords

monoesterification; dibutyltin oxide; benzoic acid

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A new facile method for moncesterification of diols has been developed. A variety of diols, in particular oligoethylene glycols, were selectively monoesterified in excellent yields by reaction with aromatic and aliphatic acids in the presence Of Al2O3/MeSO3H as a new reagent without use of any solvents. (C) 2003 Elsevier Science Ltd. All rights reserved.

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